By R. A. Sheldon, Isabella Arends, Ulf Hanefeld
''Written by means of Roger A. Sheldon and his co-workers, this primary e-book to target catalytic strategies from the point of view of eco-friendly chemistry provides each vital element: a variety of catalytic mark downs and oxidation equipment; solid-acid and solid-base catalysis; C-C bond formation reactions; biocatalysis; uneven catalysis; novel response media like e.g. ionic beverages, supercritical Co[subscript 2]; and renewable raw materials.''--BOOK JACKET. Read more...
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Edited by way of of the prime researchers within the box, this booklet offers a deep, interdisciplinary perception into stoichiometric and catalytic reactions during this continually increasing sector. A plethora of most sensible German scientists with a world attractiveness covers a number of points, from classical natural chemistry to method improvement, and from the theoretical heritage to organic tools utilizing enzymes.
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Angewandte Chemie – International Edition in English, 42, 1418–1420. , Sturmer, R. T. (2001) A highthroughput-screening method for the identiﬁcation of active and enantioselective hydrolases. Angewandte Chemie – International Edition, 40, 4201–4204. Wahler, D. L. (2002) The adrenaline test for enzymes. Angewandte Chemie – International Edition in English, 41, 1229–1232. , Lefevre, F. L. (2004) Adrenaline proﬁling of lipases and esterases with 1,2-diol and carbohydrate acetates. Tetrahedron, 60, 703–710.
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The dry gel thus obtained is called xero gel. If the water and alcohol is exchanged against acetone and then against supercritical carbon dioxide the aqua gel can be dried avoiding the capillary forces and, thus, shrinkage of the gel. The aero gel obtained in this manner has a huge pore volume but is rather brittle . The different sol gels obtained in this manner are all hydrophilic. If an alkyltrialkoxysilane such as methyltrimethoxysilane (MTMS) is added to the synthesis mixture, the sol gel prepared will have a hydrophobic surface.